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Cytrel is a synthetic compound made of cellulose developed in the 1950s to create a tobacco substitute that was safer but tasted the same

Coming to the main question, Why do lips get black due to smoking

In Canada, 94% of recreational cannabis users in 2017 reported consuming the drug by smoking marijuana 9 , a preparation of dried cannabis flowers and leaves 1

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But for vaping I think its less harmful compared to real smoking.