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Although the reaction of PhSeBr and 1a generating the SeN intermediate INT1-Se is endothermic by 12.6 kcal mol 1 , INT1-Se may readily undergo a Se-centred [2,3]-sigmatropic rearrangement to generate an ortho -Se = N substituted dearomatized species ( INT2-Se ) via TS1-Se , with a barrier of 12.7 kcal mol 1

105 KerrJRGoughJRichardsSCMainJEnlanderDMcCrearyMet al

The once-daily oral GLP-1 RA orforglipron produces clinically and statistically significant weight loss and cardiometabolic improvements, with safety comparable to that of injectable agents

doi: 10.1186/s40170-015-0132-6 56 BudzikGPCollettiLMFaltynekCR

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