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Two pairs of oxidation-reduction peaks were observed in the cyclic voltammetry curve of TMB in the acetate buffer (pH=4.0, Fig

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Monometallic examples of the former include TiCl 4 , VO 4 3 - , WS 4 2 - , MnO 4 - , CrO 4 2 - , and OsO 4 while d 10 examples are [Ni(CO) 4 ], [HgBr 4 ] 2- , [ZnCl 4 ] 2- , [CdI 4 ] 2-