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While both peptides have a chemical structure that closely resembles -MSH, they differ in several important ways

Not because the solution becomes unsafe, but because it becomes ineffective

Nature 581 , 310315 (2020)

Cell culture studies In laboratory studies using 3T3-L1 adipocytes, a commonly used fat cell line, researchers found that 5-amino-1mq significantly reduced intracellular levels of 1-methylnicotinamide, confirming that it was successfully inhibiting NNMT

Forcing a reconstituted peptide solution through an extremely narrow needle (a very high gauge) with too much pressure can potentially shear the delicate protein chains