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This is because of a pigment called urochrome

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Summary: Both methylcobalamin and cyanocobalamin effectively treat B12 deficiency, with cyanocobalamin being more stable and cost-effective whilst methylcobalamin is bioactive without requiring conversion

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There are practical reasons too: B can be unstable if mixed with certain other vitamins in solution, and dosing schedules for B deficiency (pernicious anemia, for instance) may differ