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A large trial reported in 1994 (pdf) that daily megadoses of the antioxidant beta-carotene increased the risk of lung cancer in male smokers by 18 percent and a 1996 trial was stopped early after researchers discovered that high-dose beta-carotene and retinol, another form of vitamin A, increased lung cancer risk by 28 percent in smokers and workers exposed to asbestos

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10.1073/pnas.2506321122 32 TaoZ.Le Blanc JustinM.WangC.ZhanT.ZhuangH.WangP.et al (2016)

Upon the deprotonation of cysteine to the thiolate ion, it is vulnerable to oxidation and adduction by electrophiles, disrupting the proper folding and function